World champion Olena Kostevych of Ukraine won the gold medal in the women's metres air pistol competition after outduelling gold.!
| 2004 Summer Olympics | Shooting | UKR | Olena Kostevych |
| Air Pistol, 10 metres, Women(Olympic) | 1 | Gold |
| Sporting Pistol, 25 metres, Women(Olympic) | =27 |
| 2008 Summer Olympics | Shooting | UKR | Olena Kostevych |
| Air Pistol, 10 metres, Women(Olympic) | 31 |
| Sporting Pistol, 25 metres, Women(Olympic) | 26 |
| 2012 Summer Olympics | Shooting | UKR | Olena Kostevych |
| Air Pistol, 10 metres, Women(Olympic) | 3 | Bronze |
| Sporting Pistol, 25 metres, Women(Olympic) | 3 | Bronze |
| 2016 Summer Olympics | Shooting | UKR | Olena Kostevych |
| Air Pistol, 10 metres, Women(Olympic) | 28 |
| Sporting Pistol, 25 metres, Women(Olympic) | 22 |
| 2020 Summer Olympics | Shooting | UKR | Olena Kostevych |
| Air Pistol, 10 metres, Women(Olympic) | 4 |
| Air Pistol, 10 metres, Team, Mixed(Olympic) | Oleh Omelchuk | 3 | Bronze |
| Sporting Pistol, 25 metres, Women(Olympic) | 23 |